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Whip the cream: In a large bowl, whip the heavy cream until soft peaks form. Set aside.
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Make the mascarpone mixture: In another bowl, mix the mascarpone, vanilla, and powdered sugar until smooth. Gently fold in the whipped cream until the mixture is light and fluffy.
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Prepare the coffee soak: Stir the cooled espresso with the sugar. Add a small splash of liqueur if you want a deeper flavor.
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Dip the ladyfingers: Quickly dip each ladyfinger into the coffee. Do not soak them too long or they will fall apart.
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Layer the dessert: In a dish or small cups, place a layer of dipped ladyfingers. Spread a layer of the mascarpone mixture on top. Repeat the layers until you reach the top.
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Chill and finish: Cover and refrigerate for at least 4 hours, or overnight for the best texture. Before serving, dust with cocoa powder.